Factors That Control Catalytic Two- versus Four-Electron Reduction of Dioxygen by Copper Complexes
J. Am. Chem. Soc. (2012) 134, 7025
The selective 2e- reduction of O2 by 1e- reductants such as Me8Fc and Me10Fc is efficiently catalyzed by a binuclear Cu(II) complex in the presence of an acid in acetone.
Structural and Electronic Properties of Old and New A2[M(pinF)2] Complexes
Inorg. Chem. (2013) 52, 14050
New A2[M(pinF)2] complexes of Fe−Zn were prepared, fully characterized, and compared with related literature species. .